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National Repository of Grey Literature 2 records found  Search took 0.01 seconds. 
Electrochemical Properties of Mixed Self-Assembled Monolayers Based on Terpyridine Transition Metal Complexes
 Kocábová, Jana ; Nováková Lachmanová, Štěpánka ; Vavrek, František ; Valášek, M. ; Hromadová, Magdaléna
This work presents the electrochemical characterization of mixed self-assembled monolayers\n(SAMs) of [Os(terpy)2]2+ and terpyridine connected by tripodal anchoring groups to the\npolycrystalline gold bead electrode and provides a comparison with SAM based on\n[Os(terpy)2]2+ tripodal molecules without diluting terpyridine tripodal molecules. It is shown\nthat both arrangements enable reproducible preparation of well-defined compact films. The\nelectron transfer rate constant for mixed SAM was determined from cyclic voltammograms\naccording to Laviron’s analysis and compared with the rate constant obtained previously for\nSAM containing only [Os(terpy)2]2+ tripod.
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Fluorinated macrocycles for 19F MRI
 Šmelko, Andrej ; Hermann, Petr (advisor) ; Blahut, Jan (referee)
19 F MRI contrast agents are relatively new, developing field of medical and chemical sciences. In this Theses, based on previous results in this area, new type of Ni2+ complex with possible 19 F MRI applications was synthesized and characterized by relaxometric measurements.
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